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COMPOSITES AND MULTIPURPOSE COATINGS
ArticleName Formation of oxide coatings on aluminum alloy 7075 by microarc oxidation
DOI 10.17580/tsm.2025.10.08
ArticleAuthor Bashkov О. V., Lu Lan, Bao Fengyuan, Zhao Zidong, Bashkova Т. I.
ArticleAuthorData

Komsomolsk-na-Amure State University, Komsomolsk-on-Amur, Russia

О. V. Bashkov, Head of the Department of Materials Science and Technology of New Materials, Doctor of Technical Sciences, Professor, e-mail: bashkov_ov@mail.ru

Zhao Zidong, Postgraduate Student of the Department of Materials Science and Technology of New Materials, e-mail: 379917387@qq.com
Т. I. Bashkova, Associate Professor of the Department of Materials Science and Technology of New Materials, Candidate of Technical Sciences, Associate Professor, e-mail: telem01@mail.ru

 

Heilongjiang University of Science and Technology, Harbin, China
Lu Lan, Head of the International Department, Candidate of Technical Sciences, e-mail: lvlan1980@163.com

 

Harbin University of Science and Technology, Harbin, China

Bao Fengyuan, Associate Professor at the School of Materials Science and Chemical Engineering, Candidate of Technical Sciences, Associate Professor, e-mail: bao5413@qq.com

Abstract

Microarc oxidation (MAO) is one of the modern, but not widely used methods for forming a valve group of protective oxide layers on metals. The method is most widely used in the oxidation of aluminum, magnesium, and titanium alloys in order to create protective coatings on them. The advantages of the method are the possibility of obtaining sufficiently thick coatings and the environmental friendliness of the process due to the use of low-concentration salt solutions. The mechanical properties and technological parameters of oxide coatings formed on aluminum alloy 7075 by the MAO method have been studied. The coatings were formed on flat samples at different values of current density, oxidation period, and inductance of the electrical circuit. The formation of the research plan and the analysis of the results were carried out using the planning of a full-scale experiment. Optical and electron microscopy methods were used to determine the thickness and morphology of the surface of the oxide coatings. A portable digital meter has measured the surface roughness of the coatings. The microhardness of the coatings according to Vickers was determined in the cross section. It has been found that an increase in the duration of the oxidation period from 60 to 120 minutes with a constant average current density in the electrical circuit of 15.66 A/dm2 leads to a monotonous increase in the thickness and roughness of the oxide coatings. The introduction of an inductance in the range of 0.52–53.1 Mh into an electrical circuit changes the shape, filling factor and amplitude of current pulses, and also has a nonlinear effect on the thickness and microhardness of the formed coatings.
The research was conducted at the Central Research Institute “New Materials and Technologies” of the Federal State Budgetary Educational Institution of Higher Education Komsomolsk-on-Amur State University with the financial support of a grant from the President of the Russian Federation for state support of leading scientific schools of the Russian Federation (project NSH-452.2022.4).

keywords Microarc oxidation, aluminum alloy 7075, oxide layer, thickness, microhardness, roughness, pulse, inductance
References

1. Yerokhin A. L., Nie X., Leyland A. et al. Plasma electrolysis for surface engineering. Surface and Coatings Technology. 1999. Vol. 122, No. 2–3. pp. 73–93. DOI: 10.1016/S0257-8972(99)00441-7
2. Suminov I. et al. Plasma-electrolytic modification of the surface of metals and alloys: in 2 volumes; under the general editorship of I. Suminov. Moscow : Tekhnosfera. 2011. 22 p.
3. Gordienko P. S., Dostovalov V. A., Efimenko A.V. Microarc oxidation of metals and alloys. Vladivostok : Publishing House of the Far Eastern Federal University, 2013. 521 p.
4. Sedelnikova M. B., Sharkeev Yu. P., Komarova E. G., Tolkacheva T. V. Influence of microarc oxidation process parameters on the formation and properties of bio coatings based on wollastonite and calcium phosphates. Fizika i khimiya obrabotki materialov. 2016. No. 6. pp. 57–63.
5. Komarova E. G., Sharkeev Yu. P., Chebodaeva V. V. Influence of microarc oxidation parameters on the roughness and wettability of calcium phosphate coatings. Izvestiya Vuzov. Fizika. 2014. Vol. 57, No. 10–3. pp. 171–175.
6. Krishtal M. M. Oxide layer formation by micro-arc oxidation on structurally modified Al – Si alloys and applications for large-sized articles manufacturing. Advanced Materials Research. 2009. Vol. 59. pp. 204–208. DOI: 10.4028/3-908454-01-8.204
7. Bao F., Bashkov O. V., Zhang D. et al. Study of the effect of microarc oxidation modes on the morphology and parameters of the oxide coating applied to aluminum alloy D16AT. Frontier Materials & Technologies. 2023. No. 1. pp. 7–21. DOI: 10.18323/2782-4039-2023-1-7-21
8. Bao F., Lui L., Bashkov O. V. Fatigue failure of aluminum alloy 1163 with different morphology of the oxide coating. Uprochnyayushchie tekhnologii i pokrytiya. 2024. Vol. 20, No. 1. pp. 3–7. DOI: 10.36652/1813-1336-2024-20-1-3-7
9. Malyshev V. N., Zorin K. M. Features of microarc oxidation coatings formation technology in slurry electrolytes. Applied Surface Science. 2007. Vol. 254, No. 5. pp. 1511–1516. DOI: 10.1016/j.apsusc.2007.07.079
10. Pospelov A. V., Kasach A. A., Kharitonov D. S. et al. The effect of plasmaelectrolytic oxidation parameters on the composition, structure, and surface properties of the WE43 magnesium alloy doped with rare earth elements. Fizikokhimiya poverkhnosti i zashchita materialov. 2024. Vol. 60, No. 1. pp. 75–90. DOI: 10.31857/S0044185624010084
11. Sedelnikova M. B., Blagodchikova A.V., Uvarkin P. V. et al. Structural, morphological and adhesive properties of calcium phosphate coatings formed on a magnesium alloy by microarc oxidation in an electrolyte containing dispersed particles. Izvestiya Vuzov. Fizika. 2021. Vol. 64, No. 5. pp. 60–67. DOI: 10.17223/00213411/64/5/60
12. Gordienko P. S., Vasilenko O. S., Kharchenko U. V. et al. The influence of borehole on cathodic relaxation processes and electrochemical properties of formed coatings on titanium. Perspektivnye materialy. 2013. No. 11. pp. 59–64.
13. Gordienko P. S., Dostovalov V. A., Zhevtun I. G. et al. Microarc oxidation with pulsed polarization in galvanodynamic mode. Elektronnaya obrabotka materialov. 2013. Vol. 49, No. 4. pp. 35–42.
14. Rybalko A.V., Sakhin O. O., Mesyats A. A. Some features of the microarc oxidation process at high current densities. Metalloobrabotka. 2010. No. 2(56). pp. 30–38.
15. Rodriguez L., Paris J. Y., Denape J., Delbé K. Micro-arcs oxidation layer formation on aluminium and coatings tribological properties – a review. Coatings. 2023. Vol. 13, No. 2. 373. DOI: 10.3390/coatings13020373
16. Dudareva N. Yu., Kolomeychenko A. V., Deev V. B., Zaynullina L. I. Effect of the chemical composition of aluminium alloys on the structure and properties of micro-arc oxidation coatings. Tsvetnye Metally. 2023. No. 11. pp. 62–67.
17. Kuruveri U. B., Panemangalore D. B., Kuruveri S. B. et al. Surface modification of 6xxx series aluminum alloys. Coatings. 2022. Vol. 12, No. 2. DOI: 10.3390/coatings12020180
18. Barati N., Jiang J., Meletis E. I. Microstructural evolution of ceramic nanocomposites coated on 7075 Al alloy by plasma electrolytic oxidation. Surface and Coatings Technology. 2022. Vol. 437. pp. 128345. DOI: 10.1016/j.surfcoat.2022128345
19. Lv P., Zhang X., Yin T. et al. Processing and analysis of micro-arc oxidation coating on 319S aluminum alloy. Coatings. 2023. Vol. 13, No. 6. 1024. DOI: 10.3390/coatings13061024
20. Dzhurinskiy D. V., Dautov S. S., Shornikov P. G., Akhatov I. S. Surface modification of aluminum 6061-O Alloy by plasma electrolytic oxidation to improve corrosion resistance properties. Coatings. 2021. Vol. 11, No. 1. pp. 1–13. DOI: 10.3390/coatings11010004
21. Yang Ch., Zhu J., Cui S. et al. Wear and corrosion resistant coatings prepared on LY12 aluminum alloy by plasma electrolytic oxidation. Surface and Coatings Technology. 2021. Vol. 409. 126885. DOI: 10.1016/j.surfcoat.2021.126885
22. Dudareva N. Yu., Kolomeichenko A. V., Deev V. B. Corrosion resistance of ceramic coatings formed by microarc oxidation on aluminium alloy AK4-1. Tsvetnye Metally. 2024. No. 3. pp. 26–33.
23. Dudareva N. Yu., Kolomeychenko A. V., Deev V. B., Sitdikov V. M. Corrosion resistance of oxide layers formed by micro-arc oxidation on hypereutectic aluminum alloy. Tsvetnye Metally. 2023. No. 10. pp. 56–61.
24. Egorkin V. S., Vyaly I. E., Izotov N. V. et al. Corrosion resistance in marine conditions of AMg3 aluminum alloy treated with short-pulse plasma electrolytic oxidation. Morskie intellektualnye tekhnologii. 2021. No. 4–1. pp. 117-121. DOI: 10.37220/MIT.2021.54.4.041
25. Erokhin A. L., Lyubimov V. V., Ashitkov R. V. A model for the formation of oxide coatings during plasma-electrolytic oxidation of aluminum in silicate solutions. Fizika i khimiya obrabotki materialov. 1996. No. 5. pp. 39–44.
26. Kuznetsov Yu. A., Kosenko A., Lugovskoy A., Zinigrad M. The influence of the electrolyte silicate index on the PEO process of aluminum alloys. Nanomaterials for the protection of industrial and underground structures and Solid State Physics (FTT-XI): Proceedings of the International Symposium, XI International Conference. Ust-Kamenogorsk : D. Serikbayev East Kazakhstan Technical University. 2010. pp. 370–377.
27. Hussein R. O., Nie X., North D. O. Wood The application of plasma electrolytic oxidation (PCO) to the production of corrosion resistant coatings on magnesium alloys: A review. Corrosion and Materials. 2013. Vol. 38, No. 1. pp. 54–65.
28. Mikheev A. E., Girn A.V., Vakhteev E. V. et al. The process of forming the structure and composition of MAO coatings on aluminum alloys. Bulletin of the Siberian State Aerospace University named after academician M. F. Reshetnev. 2013. No. 2. pp. 206–212.
29. Bashkov O. V., Bao F., Bashkova T. I. A method for monitoring and controlling the microarc oxidation process. Patent RF, No. 2794643. Applied: 12.09.2022. Published: 24.04.2023.
30. Bashkov O. V., Bao F., Bashkova T. I. et al. A method for monitoring and controlling the microarc oxidation process using the acoustic emission method. Patent RF, No. 2807242. Applied: 21.02.2023. Published: 13.11.2023.
31. Gordienko P. S., Panin E. S., Dostovalov V. A., Usoltsev V. K. Voltage characteristics of the metal-oxide-electrolyte system during polarization of electrodes by pulsed voltage. Fizikokhimiya poverhnosti i zashchita materialov. 2009. Vol. 45, No. 4. pp. 433–440.

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