Журналы →  Obogashchenie Rud →  2023 →  №1 →  Назад

BENEFICIATION PROCESSES
Название Research into combined flotation regimes using special slurry preparation methods
DOI 10.17580/or.2023.01.03
Автор Prokhorov K. V., Kopylova A. E., Burdonov A. E.
Информация об авторе

Mining Institute, Far East Branch of Russian Academy of Science (Khabarovsk, Russia):

Prokhorov K. V., Leading Researcher, Candidate of Engineering Sciences, kostyan1986_ne@mail.ru
Kopylova A. E., Junior Researcher

 

Irkutsk National Research Technical University (Irkutsk, Russia):
Burdonov A. E., Associate Professor, Candidate of Engineering Sciences

Реферат

This paper studies a combined flotation regime with the liquid phase represented by an electrolysis product slurry of the initial material solution, which consisted of pneumoflotation tailings of gold-quartz formation ores and contained dispersed gold. The paper substantiates the method of staged flotation in electrolysis products, initially prepared on the basis of a catholyte, with subsequent introduction of a certain amount of anolyte, allowing to increase the concentrate yield by recovering the finest particles of the valuable component. Preliminary electrochemical treatment of the solution in the anode and cathode chambers of the electrolysis cell ensured its pH and Еh conditioning and facilitated generation of microbubbles of flotationactive hydrogen and oxygen immediately before slurry preparation for flotation. The resulting increase in the flotation concentrate yield through the recovery of the finest particles of valuable components has been experimentally confirmed. Flotation in a preliminarily prepared catholyte and batchwise addition of anolyte to the catholyte have improved gold and silver recovery into the concentrate by 25 and 17 %, respectively. Flotation using electrolysis products is therefore deemed effective. Batch mixing of catholyte and anolyte serves as a mechanism for ensuring the optimal values for those parameters that affect the recovery of valuable components.
The research was carried out using the resources of the Center for the Collective Use of Scientific Equipment «Center for Processing and Storage of Scientific Data of the Far Eastern Branch of the Russian Academy of Sciences», funded by the Ministry of Science and Higher Education of the Russian Federation, under project No. 075-15-2021-663.

Ключевые слова Gold, silver, flotation, electrochemical potential, recovery, slurry, catholyte, anolyte
Библиографический список

1. Ivanov V. V., Kononov V. V., Ignatiev E. K. Mineralogical and geochemical features of ore mineralization in metasomatites of the Malmyzh gold- copper ore field (Lower Amur region). Tectonics, deep structure and mineralogy of East Asia. VIII Kosygin Readings. Proc. of the All-Russian conference, September 17–20, 2013. Vladivostok: Dalnauka. pp. 258–261.
2. Sekisov A., Rasskazova A. Assessment of the possibility of hydrometallurgical processing of low-grade ores in the oxidation zone of the Malmyzh Cu-Au porphyry deposit. Minerals. 2021. Vol. 11, Iss. 1. DOI: 10.3390/min11010069.
3. Sekisov A. G., Lavrov A. Yu., Shevchenko Yu. S., Manzyrev D. V., Petukhov A. A., Konareva T. G. Geotechnologies of extraction of dispersed and «thin» gold from technogenic mineral formations of the Trans-Baikal Territory. Vestnik Chitinskogo Gosudarstvennogo Universiteta. 2012. No. 1. pp. 34–42.
4. Jacques S., Greet C. J., Bastin D. Oxidative weathering of a copper sulphide ore and its influence on pulp chemistry and flotation. Minerals Engineering. 2016. Vol. 99. pp. 52–59.
5. Hintikka V. V., Leppinen J. O. Potential control in the flotation of sulphide minerals and precious metals. Minerals Engineering. 1995. Vol. 8, Iss. 10. pp. 1151–1158.
6. Xu Sh., Zanin M., Skinner W., Abreu S. Surface chemistry of oxidised pyrite during grinding: ToF-SIMS and XPS surface analysis. Minerals Engineering. 2021. Vol. 170. DOI: 10.1016/j.mineng.2021.106992
7. Chanturia E. L. Study of the effect of catholyte on the processes of oxidation of grinding bodies and the opening of minerals during wet grinding of rare metal, tin and tungsten ores. Obogashchenie Rud. 2004. No. 4. pp. 23–27.
8. Chanturiya E. L., Chanturiya V. A., Zhuravleva E. S. Prospects of application of water preparation of electrochemical technology in copper-zinc ores flotation. Tsvetnye Metally. 2016. No. 1. pp. 13–19. DOI: 10.17580/tsm.2016.01.02
9. Chanturiya E. L., Vishkova A. A., Ananiev P. P., Tomskaya E. S., Koporulina E. V. Enhancement of ore grinding under energy deposition. Gornyi Zhurnal. 2014. No. 12. pp. 63–69.
10. Chanturia V. A., Shadrunova I. V., Medyanik N. L., Mishurina O. A. Technology of electroflotation extraction of manganese from technogenic hydromineral raw materials of copper-pyrite deposits of the Southern Urals. Fizikotekhnicheskie Problemy Razrabotki Poleznykh Iskopayemykh. 2010. No. 3. pp. 89–97.
11. Brodsky V. A., Ilyin V. I., Kolesnikov V. A. Influence of physico-chemical characteristics of the dispersed phase of poorly soluble non-ferrous metal compounds on the efficiency of their electroflotation extraction from aqueous solutions. Teoreticheskie Osnovy Khimicheskoy Tekhnologii. 2015. Vol. 49, No. 2. pp. 144–150.
12. Alekhina E. N., Barieva E. R. Improving the efficiency of wastewater at a chemical industry enterprise using electroflotation. Sovremennye Innovatsii. 2018. No. 3. pp. 11–12.
13. Karataev O. R., Kudryavtseva E. S., Mingazetdinov I. Kh. General and special cases of using electrochemical methods of flotation purification. Vestnik Kazanskogo Tekhnologicheskogo Universiteta. 2014. Vol. 17, No. 8. pp. 63–65.
14. Salman R. H. Removal of manganese ions (Mn2+) from a simulated wastewater by electrocoagulation / electroflotation technologies with stainless steel mesh electrodes: Process optimization based on Taguchi approach. Iraqi Journal of Chemical and Petroleum Engineering. 2019. No. 20. pp. 39–48.
15. Kyzas G. Z., Lazaridis N. K., Matis K. A. Flotation: Recent innovations in an interesting and effective separation process. Interface Science and Technology. 2019. No. 30. pp. 15–42.

16. Han M. Y., Kim M. K., Ahn H. J. Effects of surface charge, micro-bubble size and particle size on removal efficiency of electro-flotation. Water Science & Technology. 2006. Vol. 53. No. 7. pp. 127–132.
17. Chanturiya V. А., Vaisberg L. A., Kozlov А. P. Promising trends in investigations aimed at all-round utilization of mineral raw materials. Obogashchenie Rud. 2014. No. 2. pp. 3–8.
18. Hacha R. R., Merma A. G., Couto H. J., Torem M. L. Measurement and analysis of H2 and O2 bubbles diameter produced by electroflotation processes in a modified Partridge-Smith cell. Powder Technology. 2019. Vol. 342. pp. 308–320.
19. Prokhorov K. V., Kopylova A. E. Promising methods for intensifying the process of flotation of copper-porphyry and gold-silver ores by using electrochemical treatment. Problemy Nedropolzovaniya. 2020. No. 2. pp. 96–106.
20. Prokhorov K. V., Poltaretskaya A. E. Effect of electrochemical control of the process of selective flotation of copper, iron from complex ores. Problems and prospects of effective processing of mineral raw materials in the 21st century (Plaksin Readings – 2019). Proc. of the International meeting. 2019. pp. 198–201.
21. Prokhorov K. V., Gladyr A. V., Rasskazov M. I. Center for collective use «Center for research of mineral raw materials». Gornaya Promyshlennost'. 2020. No. 4. pp. 120–124.
22. Sekisov A. G., Lavrov A. Yu., Rubtsov Yu. I., Rasskazova A. V., Konareva T. G. Physico-chemical geotechnologies of the development of deposits of the Far Eastern Federal District. Chita: ZabSU, 2021. 305 p.
23. Chanturia V. A., Nazarova G. N. Electrochemical technology in beneficiation and hydrometallurgical processes. Moscow: Nauka, 1977. 160 p.
24. Chanturia V. A., Lunin V. D. Electrochemical methods of intensification of the flotation process. Moscow: Nauka, 1983. 144 p.

Language of full-text русский
Полный текст статьи Получить
Назад